The synthesis of carbon-based chemicals through the electrochemical reduction of carbon dioxide (CO2) has been a major focus of energy research in recent years. While significant progress has been made in this field, many of the proposed methods lack energy efficiency and selectivity. One such example is the production of the hydrocarbon ethylene, which has not yet achieved the desired level of efficiency and stability. This has hindered its widespread adoption as an alternative to traditional methods of ethylene production that are harmful to the environment.

Researchers at Université Montpellier and other institutions have been exploring ways to improve the selective and energy-efficient synthesis of ethylene through the reduction of CO2. Their recent study, published in Nature Energy, introduces a novel approach to functionalize copper (Cu) catalysts for CO2 reduction using aryl diazonium salts. By modifying the catalysts with these salts, the researchers were able to enhance the selectivity towards multi-carbon products, particularly ethylene.

Experimental Results

Through a series of calculations and experiments, the researchers discovered that different aryl diazonium salts could be used to customize the oxidation state of copper. This customization allowed for the functionalization of catalysts in a membrane electrode assembly (MEA) cell, which is crucial for facilitating electrochemical reactions, including those involved in the reduction of CO2. The team tested the performance of this MEA flow cell with tailored Cu sites and observed improved energy efficiency and stability in the reduction of CO2 to produce ethylene.

The researchers reported that by tuning the oxidation state of copper through functionalization, they were able to significantly enhance the selectivity for ethylene production. They achieved a Faradaic efficiency of 83% and a specific current density of 212 mA/cm^2 for ethylene, indicating a substantial improvement in energy efficiency. The use of CO gas feed resulted in an overall energy efficiency of approximately 40%, with a Faradaic efficiency of 86% for ethylene production.

This study by a team of dedicated researchers presents a promising strategy for the energy-efficient and stable synthesis of ethylene from CO2. By focusing on valence engineering of copper catalysts, they have opened up new possibilities for sustainable methods of ethylene production on a large scale. Further refinement and validation of this strategy could play a significant role in driving the transition towards more environmentally friendly practices in the chemical industry.

Chemistry

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